Q.

Liquid A and B  from ideal solution over the entire range of composition. At the temperature T, equimolar binary solution of liquids A and B has vapour pressure 40 torr.  At the same temperature, a new solution of A and B having mole fractions XA and XB, respectively, has vapour pressure of 20 torr. The value of XA/XB in the  new solution is ( given that the vapour pressure of pure liquid A is 10 torr at temperature T ) 
 

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answer is 5.

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Detailed Solution

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PA0×12+PB0×12=40PA0+PB0=8010+PB0=80PA0=10PB0=7010xA+701xA=20xA=0.8,xB=0.2xAxB=4

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