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Q.

LIST - 1                                      LIST - 2

Compound                               C-C bond length

A) Benzene                               1) 1.42A°

B) Acetylene                             2) 1.54A°

C) Graphite                               3) 3.35A°

D) Diamond                              4) 1.20A°

                                                     5) 1.39A°

The correct match is

A  B  C  D

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a

4  5  1  2

b

1  4  2  3

c

5  4  1  2

d

2  3  4  5

answer is C.

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Detailed Solution


C-C  1.54A°

C=C  1.34A°

CC  1.20A°

Benzene

Question Image

All C−C and C=C bond lengths are the same in benzene due to resonance. Hence, C−C bond length in benzene is 1.39A° (in the middle of C-C and C=C bond lengths)

Acetylene (Ethyne)

                           CHCH

So, bond length of CC  is 1.20A°

Graphite

solution

Graphite has both C−C and C=C bonds and bond length of C=C in graphite is 1.42A°

Diamond

Diamond

Diamond only has C-C single bonds thus the bond length is 1.54A°

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