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Q.

 LIST - 1 LIST - 2
A)N2Oi)sp2 and planar triangle
B)HNO2ii)Nitrite and nitro form
C)NO3iii)sp3 and tetrahedron
D)HNO4iv)Laughing gas
  v)Peroxy bond
 (A)(B)(C)(D)
1)iiiiiiiv
2)iiiiiivi
3)iiviiiiv
4)iviiiv

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a

2

b

1

c

3

d

4

answer is D.

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Detailed Solution

4)iviiiv

Laughing gas is N2O (nitrous oxide). Hence, A matches with iv.

Nitrous acid exists in two tautomeric forms
(1) nitro form as in nitro alkanes
(2) nitrite form as in alkyl nitrite

Hence, B matches with ii.

In NO3, N has sp2 and molecule has planar triangle shape. Hence, C matches with i.

Structure of HNO4 is shown below which shows that there is one peroxy bond. Hence, D matches with v.

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