Q.

 LIST - I (complex) LIST - II (Charge on co-ord. sphere)
A)CoCl3.6NH3i)+1
B)CoCl3.5NH3ii)+2
C)CoCl3.4NH3iii)+3
D)CoCl3.3NH3iv)+4
  v)0

The correct match in terms of the charge on the complex
 

 ABCD
1iiiiivi
2iiiiiiv
3iiiiiiv
4iviiiiii

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a

2

b

1

c

3

d

4

answer is C.

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Detailed Solution

CoCl3.6NH3 can form complex ,  [Co(NH3)6]Cl3.

[Co(NH3)6]Cl3 [Co(NH3)6] 3+ + 3Cl -

CoCl3.5NH3 can form  complex ,  [Co(NH3)5Cl] Cl2.

[Co(NH3)5Cl]Cl2 [Co(NH3)5Cl] ++ 2Cl -

CoCl3.4NH3 can form  complex ,  [Co(NH3)4Cl2] Cl.

[Co(NH3)4Cl2]Cl [Co(NH3)4Cl2]+1 + Cl -

CoCl3.3NH3can form  complex ,  [Co(NH3)3Cl3] .

[Co(NH3)3Cl3] [Co(NH3)3Cl3].

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