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Q.

List -I                               List - II

A) Boyle's law               1) P obs = Patm+ Pwater vapour

B) Avagadro law             2) {{V}_{1}}=\,{{n}_{1}}\left ( \frac{{{V}_{2}}}{{{n}_{2}}} \right )

C) Charles law                3) {{V}_{t}}=\,{{V}_{o}}\left ( 1+\frac{t}{273} \right )

D) Dalton's law                4) {{V}_{1}}=\,{{P}_{2}}\left ( \frac{{{V}_{2}}}{{{P}_{1}}} \right )

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a

A      B      C      D

1       2       3      4

b

A      B      C      D

2       3       4       1

c

A      B      C      D

4       3       2       1

d

A      B      C      D

4        2      3       1

answer is D.

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Detailed Solution

Boyle's law

P1V= P2V2  \Rightarrow \frac{P_1}{V_2}=\frac{P_2}{V_1}

Avogdro's law : V\propto\;n; P,T are constant

\frac{V_1}{n_1}\;=\frac{V_2}{n_2}

Charle's law

V\propto\;T;\;n,T\;are\;kept\;constant\;\frac{V}{T}=constant

The given statements are based on observations of Charle's experiment and Kelvin scale.

{V_{T\,}} = \,{V_0}\,\left( {1 + \frac{{\Delta T}}{{273}}} \right)

Vis the volume 0oC and  ΔT is the rise in temperature keeping pressure constant. VT is the volume of the system at constant pressure. 

T = 0oC + ΔT

Dalton's law

Pobs = Patm + Pwater vapour

vapours follow Dalton's law of partial pressures.

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