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List – I (complex) List – II (Charge on co – ord. sphere)
A) $C o C l_{3} .6 N H_{3}$ 1) +1
B) $C o C l_{3} .5 N H_{3}$ 2) +2
C) $C o C l_{3} .4 N H_{3}$ 3) +3
D) $C o C l_{3} .3 N H_{3}$ 4) +4
5) 0
The correct match in terms of the charge on the complex

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A - 3, B - 2, C - 5, D - 1

A - 3, B - 1, C - 2, D - 5

A - 3, B - 2, C - 1, D - 5

A - 4, B - 3, C - 2, D - 1

answer is C.

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Detailed Solution

$C o C l_{3} .6 N H_{3} \Rightarrow [C o {(N H_{3})}_{6}] C l_{3} \to {[C o {(N H_{3})}_{6}]}^{+ 3} + 3 C l^{-}$

$C o C l_{3} .5 N H_{3} \Rightarrow [C o {(N H_{3})}_{5} C l] C l_{2} \to {[C o {(N H_{3})}_{5} C l]}^{+ 2} + 2 C l^{-}$

$C o C l_{3} .4 N H_{3} \Rightarrow [C o {(N H_{3})}_{4} C l_{2}] C l \to {[C o {(N H_{3})}_{4} C l_{2}]}^{+} + C l^{-}$

$C o C l_{3} .3 N H_{3} \Rightarrow [C o {(N H_{3})}_{3} C l_{3}] C l \to N o i o n s$

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