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List –I (Complex)
List –II (Charge on
Co-ord. Sphere
A) $C o C l_{3} .6 N H_{3}$ 1) +1
B) $C o C l_{3} .5 N H_{3}$ 2) +2
C) $C o C l_{3} .4 N H_{3}$ 3) +3
D) $C o C l_{3} .3 N H_{3}$ 4) +4
5) 0
The correct match in terms of the charge on the complex

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A-3, B-2, C-5, D-1

A-3, B-1, C-2, D-5

A-3, B-2, C-1, D-5

A-4, B-3, C-2, D-1

answer is C.

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Detailed Solution

${CoCl}_{3} .6 {NH}_{3} \to {[Co {({NH}_{3})}_{6}]}^{3 +} + 3 {Cl}^{-} . {CoCl}_{3} . 5 {NH}_{3} \to {[Co {({NH}_{3})}_{5} Cl]}^{2 +} + 2 {Cl}^{-} . {CoCl}_{3} . 4 {NH}_{3} \to {[Co {({NH}_{3})}_{4} {Cl}_{2}]}^{+} + {Cl}^{-} . {CoCl}_{3} . 3 {NH}_{3} \to [Co {({NH}_{3})}_{3} {Cl}_{3}] .$

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