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Q.

 

List – I

 

List – II

A

[NiCl4]2–

P

Square planar

B

[Ni(CO)4]

Q

Paramagnetic

C

[Co(NH3)6]3+

R

Tetrahedral

D

[Ni(CN)4]2–

S

Diamagnetic

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a

A – R, S; B – R, Q; C – S; D – P, Q

b

A – R, S; B – R, S ; C – Q; D – P, Q

c

A – R, Q; B – R, S; C – Q; D – P, S

d

A – R, Q; B – R, S; C – S; D – P, S

answer is D.

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Detailed Solution

[NiCl4]2–    -sp3- Tetrahedral - Paramagnetic

[Ni(CO)4]  -sp3- Tetrahedral - Diamagnetic

[Co(NH3)6]3+-d2sp3- Octahedral - Diamagnetic

[Ni(CN)4]2– -dsp2 - Square planar - Diamagnetic

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