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Q.

 List-I List-II
P)Bi3+gives black precipitate withI)Saturated solution of H2S in water
Q)Cu2+gives black precipitate withII)Potassium thiocyanate solution
R)Zn2+gives white precipitate withIII)Potassium iodide solution
S) IV)Potassium ferrocyanide solution
  V)Potassium chloride
 (P)(Q)(R)(S)
1)I,IIII,IVII,IV,V
2)I, IIII, III, IVII, IV ,V
3)II, III , IVII, III, IV, V
4)I,IIII ,IIV,IVII, IV,V

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a

2

b

1

c

3

d

4

answer is A.

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Detailed Solution

A) 2Bi3++3H2SBi2S3( black )+6H+
B) Cu2++H2S  CuSblack+2H+Cu2++2SCN  CuSCN2blackWhich on standing slowly changes to white2CuSCN2  CuSCN2black Cu2I2is white precipitate andCu2FeCN6brown precipitate.
(C) Zn2++H2SZnS( white )+2H+2K++2Fe(CN)64+3Zn2+K2Zn3Fe(CN)62( white )ZnI2 solube (D) 4Ag++Fe(CN)64Ag4Fe(CN)6( white )Ag++SCNAgSCN( white )Ag++ClAgCl( white )Agg2S black; AgI  yellow 
 

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