Q.

List the following dienes in decreasing order of their reactivity in Diels-Alder reaction.

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a

i > ii > iv > iii 

b

iv > iii > i > ii

c

iv > i > ii > iii 

d

iv > i > iii > ii
 

answer is B.

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Detailed Solution

(iv) is most reactive because dienes is locked in cis conformation, Diels- Alder favourable in cis form
(ii) is least reactive
(i) is more than (iii)
(ii) is least reactive
Hence, the correct answer is (B).

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