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Q.

Lithium has a bcc structure. Its density is 530kgm3 and its atomic mass is 6.94gmol1 Calculate the edge length of a unit cell of Lithium metal. NA=6.02×1023mol1

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a

154pm

b

352pm

c

527pm

d

264pm

answer is B.

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Detailed Solution

ρ=Z×NNA×a3

For bcc structure

Z=2,ρ=530kgm3=0.530gcm30.530=2×6.946.02×1023×a3

a3=4.348×1023cm3a=3.52×108cma=352pm

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