Q.

ln which of the following molecular shape dz2-orbital  must not be involved in bonding ?

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a

Square planar

b

Pentagonal planar

c

Trigonal planar

d

Linear

answer is B.

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Detailed Solution

(1)  Pentagonal planar sp3d3s+px+py+pz+dx2y2+dz2+dxy

(2)  Trigonal planar sp2[s+ Any two p]

(3)  Linear  sp2[s+ any one p]

                     sp2[s+ any two p]sp3s+px+py+pzsp3ds+px+py+pz+dz

(4)  Square planar sp3d2s+px+py+pz+dx2y2+dz2

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