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Q.

Low spin complex of d6 – cation in an octahedral field will have the following energy [o = crystal field splitting energy, p = pairing energy]

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a

2.4Δ0+p

b

2.4Δ0+2p

c

0.6Δ0

d

2.4Δ0+3p

answer is A.

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Detailed Solution

Low spin complex of d6 cation having Δ0​> P.E
Configuration is t2​g6eg0 and 3 electron are paired in t2g​​ orbital
= (- 0.4 ​t2​g+0.6eg) Δ0+3P

= (- 0.4 ​×6 +0.6 ×0) Δ0+3P
= - 2.4 ​Δ0​+3P

solution


 

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