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Q.

L.U.P.A.C. name for complex MnπC5H5(CO)3

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a

 Tricarbonyl η5 cyclopentadiene  manganese (I) 

b

 Tricarbonyl η5-cyclopentadienyl)manganese (I) 

c

 Tricarbonyl η5 cyclopentadiene  mangate (I) 

d

 ( η5-cyclopentadienyl) tricarbonyl manganese (I) 

answer is C.

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Detailed Solution

I.U.P.A.C name for [Mn(π−C​5H5​)(CO)3​]is 

Tricarbonyl (η5-cyclopentadienyl)manganese(I)

In this complex CO is a neutral ligand so it will named first followed by C5​H5​ but as it is a π bonded ligand and has five carbons so it is named as η5-cyclopentadienyl. C5​H5​ has +1 charge so overall charge and oxidation state of manganese will be +1. 

Thus, the complex is named as  Tricarbonyl (η5-cyclopentadienyl)manganese(I)

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