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Q.

$Λ_{m}^{0}$ of ${BaCl}_{2}, H_{2} {SO}_{4}$ and HCl aqueous solutions are $X_{1}, X_{2} and X_{3}$ respectively. Then $Λ_{m}^{0}$ $({BaSO}_{4}) is$

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a

$X_{1} + X_{2} - X_{3}$

b

$X_{1} + X_{2} - 2 X_{3}$

c

$X_{1} - X_{2} - X_{3}$

d

$X_{1} - 2 X_{3} - X_{3}$

answer is C.

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Detailed Solution

$\underset{_{B a S O_{4}}}{\land_{M}^{o}} = \underset{_{B a C l_{2}}}{\land_{M}^{o}} + \land_{H_{2} S O_{4}}^{o} - 2 \times \land_{H C l}^{o}$

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Λm0 of BaCl2, H2SO4 and HCl aqueous solutions are X1,X2 and X3 respectively. Then Λm0 (BaSO4)is