Q.

Magnetic moment of the following is zero

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a

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b

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c

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d

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answer is D.

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Detailed Solution

   Magnetic moment = n(n+2) BM where   n=number of unpaired electrons 

   Valence shell Configuration of  Fe+2 is  3d6 4s0 In presence of strong ligand CN-, 6e- in 3d are arranged as 3 pairs

Hence [Fe(CN)6]-4 has no unpaired electrons & it has zero magnetic moment.

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Magnetic moment of the following is zero