Q.

Major product of the following reaction is CH3Br+KCN

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a

CH3CH2CN

b

CH3NC

c

CH3NHCH3

d

CH3CN

answer is B.

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Detailed Solution

KCN being ionic in nature dissociates into K+ and CN. CN  being ambident nucleophile provides both carbon and nitrogen but attack takes place through carbon as C−C bond is stronger than C−N bond.

CH3Br+KCNCH3CN+KBr

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