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Q.

Manganese dioxide on heating with concentrated hydrochloric acid gives a greenish yellow gas, X. With excess of ammonia X gives Y and Z. Y and Z respectively are

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a

$N H_{4} I, N O C l$

b

$N H_{4} C l, N_{2}$

c

$N H_{4} F, N_{2}$

d

$N C l_{3}, H O C l$

answer is D.

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Detailed Solution

$M n O_{2} + 4 H C l (c o n c .) \to M n C l_{2} + \underset{(X)}{C l_{2}} + 2 H_{2} O$

$3 C l_{2} + 8 N H_{3} (e x c e s s) \to \underset{(Y)}{6 N H_{4}} C l + \underset{(Z)}{N_{2}}$

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