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Q.

Mark the correct statement(s)about graphite and diamond.

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a

Graphite uses sp2 hybrid orbitals and diamond uses sp3 hybrid orbitals in bonding

b

Both are insulators

c

Graphite is thermodynamically more stable

d

The graphite hexagonal layers can slide over one another and thus used as  lubricant while diamond is hard as it has 3-dimensional structure.

answer is A, B, D.

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Detailed Solution

(a) Graphite uses three electrons in bonding with sp2 hybrid orbitals and fourth electron is delocalized in πbonding. Thus, graphite is conducting.

Diamond uses four electrons in bonding with sp3 hybrid orbitals and thus non-conducting. Thus, correct

(b) Graphite consists of planer hexagonal layers of C-atoms held together by weak van der waals’ forces. Layers can slide over one another. This makes graphite a lubricant and slippery. Thus correct.

(c) Based on (a). Thus, incorrect.

(d) Diamond 0Δ Graphite. Thus, graphite is thermodynamically more stable than diamond.

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Mark the correct statement(s)about graphite and diamond.