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Q.

Match Column I with Column II related to the figure given below and then select the appropriate option from the codes given below.
 

Question Image
 Column I Column II
A.Figure represents1.Reduction
B.O2(g)+4H+(aq)+4e2H2O(l)2.Corrosion of iron of atmosphere
C.Fe(s)Fe2+(aq)+2e3.Oxidation
D.2Fe2+(aq)+2H2O(l)+12O2Fe2O3+4H+(aq)  

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a

A - 2 ; B - 3 ; C - 1 ; D - 2

b

A - 1 ; B - 2 ; C - 3 ; D - 1

c

A - 1 ; B - 2 ; C - 1 ; D - 3

d

A - 2 ; B - 1 ; C - 3 ; D - 2

answer is A.

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Detailed Solution

Given figure represents the corrosion of iron in the atmosphere. Oxidation occurs at anode and reduction occurs at cathode
Cathode = O2(g)+4H+(aq)+4e2H2O(l);                                                                EH+O2H2O=1.23V
Anode = 2Fe(s)2Fe2+(aq)+4e;EFe2+/Fe=0.44V
Overall reaction = 2Fe(s)+O2(g)+4H+(aq)2Fe2+(aq)                                                              +2H2O(l);Ecell=1.67V

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