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Q.

Match List - l with List - I and choose the correct option.

 List - I  List-II
(A)Sodium carbonate (I)Deacon Process
(B)Titanium(II)Castner-Kellner Process
(C)Chlorine (III)Van-Arkel Process
(D)Sodium hydroxide (IV)Solvay Process

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a

(A)-(I), (B)-(Ill), (C)-(lV), (D)-(ll)

b

(A)-(IV), (B)-(III), (C)-(I), (D)-(II) 

c

(A)-(III), (B)-(II), C-(I), (D)-(IV)

d

(A)-(IV), (B)-(I), (C-(II), (D)-(lll) 

answer is A.

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Detailed Solution

Solvay process used for the formation of sodium carbonate. During this process, ammonium carbonate is treated with sodium chloride to form sodium carbonate and ammonium chloride.

NH42CO3+2NaClNa2CO3+2NH4Cl

Van Arkel method is used for purify metal from its crude state (impure metal). Impure metal (Ti) first heated at 500 K with iodine to form TiI4, which is a volatile compound.

TiImpure metal+2I2500 KTiI4

TiI4 further heated at 1700 K to form pure metal.

TiI41700KTi+2I2

Deacon process is used for the formation of chlorine gas when oxygen gas is passed over HCl using catalyst copper chloride (Cu2Cl2).

4HCl+O2400°C-450°CCu2Cl22Cl2+2H2O

Sodium hydroxide (NaOH) is formed when brine solution of NaOH undergoes electrolysis in Castner Kellner process. 

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