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Q.

Match List-I with List-II.

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Choose the correct answer from the options given below.

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a

(a)    (b)    (c)    (d)

iii        i       iv       ii

b

(a)    (b)    (c)    (d)

  i       iv      iii       ii

c

(a)    (b)    (c)    (d)

iv        i       ii       iii

d

(a)    (b)    (c)    (d)

iii        iv       i       ii

answer is B.

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Detailed Solution

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Boiling point increases with increase in number of carbon atoms and decreases with branching. Option (a) has 5 carbon atoms but Option (b) has 6 carbon atoms. ∴ B.P. of (b) > (a). Option (c) and (d) have ' 5 ' carbon atoms each but option (c) has one branch and option (d) has two branches. ∴ B.P. of (c)> (d).
∴ Order of B.P. :b>a>c>d

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