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Q.

Match List-I with List-II.

 List - I List - II
A)Separation of aniline-water mixture I)Fractional distillation
B)Separation of aniline-chloroform mixture II)Distillation under reduced pressure
C)Separation of glycerol from  spent-lye III)Distillation
D)Separation of different  fraction IV)Steam distillation

Choose the correct answer from the options given below:

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a

(a)     (b)      (c)      (d)

iv        i          iii         ii

b

(a)     (b)      (c)      (d)

iv        ii          iii        i

c

(a)     (b)      (c)      (d)

iv        iii         ii         i

d

(a)     (b)      (c)      (d)

 i        iii         ii         iv

answer is C.

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Detailed Solution

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(a) Aniline is an aromatic compound, in which an amine group is present on the benzene ring, and it is a liquid that is not miscible in water. So we can separate the mixture of aniline and water by steam distillation.
(b) Separation of aniline, chloroform mixture by distillation More volatile chloroform vapourises first and is  collected in the receiver. Aniline is left in the distillation flask. 
(c) Separation of glycerol from spenlye because glycerol has a high B.P and since, in this method the external
pressure is lowered, it boils at a lower temperature.
(d) Fractional distillation is the separation of a mixture into its component parts of oil fractions. This is the process of separation of chemical compounds by their B.P the mixture is heated to a temperature at which one or more fractional or component parts will vaporise.
 

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