Q.

Match List-I with List-II.

List-I
(Complex)
List-II
(Hybridization & Magnetic characters)
(A)[MnBr4]2–(I)d2sp3 & diamagnetic
(B)[FeF6]3–(II)sp3d2 & paramagnetic
(C)[Co(C2O4)3]3–(III)sp3 & diamagnetic
(D)[Ni(CO)4](IV)sp3 & paramagnetic

Choose the correct answer from the options given below :

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a

(A)-(IV), (B)-(I), (C)-(II), (D)-(III)

b

(A)-(III), (B)-(II), (C)-(I), (D)-(IV)

c

(A)-(III), (B)-(I), (C)-(II), (D)-(IV)

d

(A)-(IV), (B)-(II), (C)-(I), (D)-(III)

answer is D.

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Detailed Solution

(A)[MnBr4]2 Mn+2[Ar]3d5

In presence of ligand field

Question Image

sp3hybridization, paramagnetic in nature

(B)[FeF6]3 Fe+3[Ar]3d5

In presence of ligand field

Question Image

sp3d2hybridization, paramagnetic in nature

(C)[Co(C2O4)3]3 Co+3[Ar]3d6

In presence of ligand field

Question Image

d2sp3hybridization, diamagnetic in nature

(D)[Ni(CO)4] Ni0[Ar]3d84s2

In presence of ligand field

Question Image

sp3hybridization, diamagnetic in nature

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