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Q.

Match of the following columns:

Column-IColumn-Il
(a) CH4(p) Molecules are associated by hydrogen bonding
(b)  H2O(q) All bond angles are 10928
(c) OCl2(r) Non-zero dipole momenl
(d) SF4(s) Zero dipole moment
 (t) Molecule is hypervalenl

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a

(a-q, s); (b-p, r); (c-r); (d-r, t)

b

(a-q, s); (b-s, r); (q-r); (d-r, t)

c

(a-p, s); (b-p, r); (c-r); (d-r, t)

d

(a-q, s); (b-q, r); (c-q); (d-r, s)

answer is A.

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Detailed Solution

The bond angle of methane CH4 is 109.5 degrees. This molecule has a dipole moment of zero.
In liquid water, hydrogen bonding occurs when the hydrogen atoms of one water molecule are drawn to the oxygen atom of a neighbouring water molecule.
Dichlorine monoxide OCl2 is an inorganic compound with nonpolar molecules and a net-zero dipole moment.
The geometry of Sf4 will be an asymmetric electron region distribution around the central atom (S). This molecule is thus polar.

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