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Q.

Match tbe following columns:

 Column-I (Molecules/ Species) Column-II (Characteristics which is/are not correct for the given molecule/species in column-I)
(a) CFClBrI (p)All possible bond angles are identical
(b)XeF4(q)Species/molecule is planar
(c)SO3(r)Species/molecule is non-planar
(d)BF2Cl(s)Species/molecule is non-polar
  (t)All possible bond angles are different

 

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a

(ap,q,s); (br,t); (cr,t); (dp,r,s,t)

b

(aq,s); (bs,t); (cp,t); (dr,s,t)

c

(ap,q);(br,s);(cp,r);(dp,t)

d

(ap,s);(bp,s,t);(cq,t);(dp,r)

answer is A.

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Detailed Solution

In CFClBrI, a carbon atom is chiral as it is bonded to four different groups. In this moelcule all the possible bond angles are not identical. Thus, it is not a planar and non-polar a molecule. 

Question Image

XeF4. Xenon tetrafluoride – XeF4 compound has a planar structure. 
SO3​ has a trigonal planar structure with bond angle 120 degree.
BF2Cl is a trigonal planar and polar molecule.
Thus, the option A is correct.

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