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Q.

Match the column 

 Column-I Column-II             
ACl2+cold and dilute NaOH PDisproportionation take place     
BCl2+hot and conc.NaOH  QChloride  (Cl) is produced
C2NaNO3500°CΔRChlorate ClO3 is produced   
DClO2+NaOH(aq)SHypochlorite (OCl)   is produced
  TChlorite (ClO2)  is produced  
  Uoxygen gas is liberated   

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a

(A P,Q,S),(B P,Q,R),(C U),(D P,R,T)

b

(AP,Q),(BQ,R),(CU),(DQ,R,T)

c

(AP,Q,S),(BP,Q,R),(CP,Q),(DP,R,T) 

d

(AP,Q,S,T,U),(BP,R,T),(CQ,U),(DP,R,T) 

answer is A.

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Detailed Solution

detailed_solution_thumbnail

(A) Cl2+cold and dilute 2NaOH00CNaCl+NaOCl+H2O               
(B) Cl2+hot and cone. 6NaOHΔ>500C5NaCl+NaClO3+3H2O           
(C) 2NaNO3Δ2NaNO2+O2              
(D) 2ClO2+H2OHClO2+HClO3       
                                          +3        +5         
     HClO2+NaOHNaClO2+H2O                                 
     HClO3+NaOHNaClO3+H2O       

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