Q.

Match the complexes in Column-I with their properties listed in Column-II.

 Column – I Column – II
A)[Co(NH3)4(H2O)2]Cl2P)Geometrical isomers
B)[Pt(NH3)2Cl2]Q)Paramagnetic
C)[Co(H2O)5Cl]ClR)Diamagnetic
D)[Ni(H2O)6]Cl2S)Metal ion with +2 oxidation state

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a

A – P, B – Q, C – R, D – S

b

A – PQS, B – PRS, C – QS, D – QS

c

A – QS, B – PR, C – PQ, D – PS

d

A – PR, B – PQS, C – QR, D – S

answer is A.

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Detailed Solution

A)  [Co(NH3)4(H2O)2]Cl2 exhibit geometrical isomerism. It is paramagnetic with  d7(Co2+) config,
B) [Pt(NH3)2Cl2]  have  pf  in + 2 oxidation state, diamagnetic, can exhibit geometrical isomerism
C)  [Co(H2O)5Cl]Cl have  Co in + 2 oxidation state with  d7 config. If is paramagnetic
D)  [Ni(H2O)6]Cl2 have  Ni in + 2 oxidation state have  t2g6eg2 config. With 2 unpaired electrons. So paramagnetic

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