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Q.
Match the compounds of Xe in column I with the molecular structure in column II.
Column I | Column II |
(a) XeF2 | (ii) Linear |
(b) XeF4 | (i) Square planar |
(c) XeO3 | (iv) Pyramidal |
(d) XeOF4 | (iii) Square pyramidal |
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a
(a)-(ii) (b)-(iv) (c)-(iii) (d)-(i)
b
(a)-(ii) (b)-(i) (c)-(iii) (d)-(iv)
c
(a)-(ii) (b)-(i) (c)-(iv) (d)-(iii)
d
(a)-(ii) (b)-(iii) (c)-(i) (d)-(iv)
answer is A.
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Detailed Solution
The correct matching between the compounds of Xenon in Column I and their molecular structures in Column II is:
(a) - (ii), (b) - (i), (c) - (iv), (d) - (iii)
Detailed Explanation:
- Xenon Difluoride (XeF2):
- This compound has a linear structure due to the presence of two fluorine atoms attached to Xenon and three lone pairs, which lead to a linear shape according to the VSEPR theory.
- Match: (a) - (ii) Linear
- Xenon Tetrafluoride (XeF4):
- This compound exhibits a square planar structure. The central Xenon atom is surrounded by four fluorine atoms with two lone pairs, forming a square planar arrangement.
- Match: (b) - (i) Square planar
- Xenon Trioxide (XeO3):
- This compound has a pyramidal structure. The central Xenon atom is bonded to three oxygen atoms with one lone pair, leading to a pyramidal shape.
- Match: (c) - (iv) Pyramidal
- Xenon Oxytetrafluoride (XeOF4):
- This compound exhibits a square pyramidal structure. It consists of four fluorine atoms and one oxygen atom bonded to Xenon with one lone pair.
- Match: (d) - (iii) Square pyramidal
Concept
- The molecular shape of compounds is determined by the number of bonding pairs and lone pairs of electrons around the central atom (VSEPR theory).
- In Xenon compounds, lone pairs and bonding pairs influence the overall geometry, giving rise to different shapes such as linear, square planar, pyramidal, and square pyramidal.
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