Q.

Match the compounds of Xe in column I with the molecular structure in column II.

Column IColumn II
(a) XeF2(ii) Linear
(b) XeF4(i) Square planar
(c) XeO3(iv) Pyramidal
(d) XeOF4(iii) Square pyramidal

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a

(a)-(ii) (b)-(iv) (c)-(iii) (d)-(i)

b

(a)-(ii) (b)-(i) (c)-(iii) (d)-(iv)

c

(a)-(ii) (b)-(i) (c)-(iv) (d)-(iii)

d

(a)-(ii) (b)-(iii) (c)-(i) (d)-(iv)

answer is A.

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Detailed Solution

The correct matching between the compounds of Xenon in Column I and their molecular structures in Column II is:

(a) - (ii), (b) - (i), (c) - (iv), (d) - (iii)

Detailed Explanation:

  1. Xenon Difluoride (XeF2):
    • This compound has a linear structure due to the presence of two fluorine atoms attached to Xenon and three lone pairs, which lead to a linear shape according to the VSEPR theory.
    • Match: (a) - (ii) Linear
  2. Xenon Tetrafluoride (XeF4):
    • This compound exhibits a square planar structure. The central Xenon atom is surrounded by four fluorine atoms with two lone pairs, forming a square planar arrangement.
    • Match: (b) - (i) Square planar
  3. Xenon Trioxide (XeO3):
    • This compound has a pyramidal structure. The central Xenon atom is bonded to three oxygen atoms with one lone pair, leading to a pyramidal shape.
    • Match: (c) - (iv) Pyramidal
  4. Xenon Oxytetrafluoride (XeOF4):
    • This compound exhibits a square pyramidal structure. It consists of four fluorine atoms and one oxygen atom bonded to Xenon with one lone pair.
    • Match: (d) - (iii) Square pyramidal

Concept

  • The molecular shape of compounds is determined by the number of bonding pairs and lone pairs of electrons around the central atom (VSEPR theory).
  • In Xenon compounds, lone pairs and bonding pairs influence the overall geometry, giving rise to different shapes such as linear, square planar, pyramidal, and square pyramidal.
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