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Q.

Match the Cp/Cv ratio for gases with different types of molecules:

Column – I

Molecule

Column – II

Cp/Cv

A) Monoatomic(I) 7/5
(B) Diatomic rigid molecules(II) 9/7
(C) Diatomic non-rigid molecules(III)4/3
(D) Triatomic rigid molecules(IV)5/3

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a

(A)-(IV), (B)-(II), (C)-(I), (D)-(III) 

b

( A)-(III), (B)-(IV), (C)-(II), (D)-(I)

c

(A)-(II),(B)-(III),(C)-(I),(D)-(IV)

d

(A)-(IV), (B)-(I), (C)-(II), (D)-(III) 

answer is C.

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Detailed Solution

γ=CpCv

γmono=53; γdi,rigid=75; 

γdi,nonrigid=97;  γtri,rigid=43

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