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Q.

Match the electronic configurations in List-I with appropriate metal complex ions in List-II and choose the correct option. [Atomic Number: Fe = 26, Mn = 25, Co = 27]
 

 List-I  List-II
(P)t2g6eg0(1)FeH2O62+
(Q)t3g3eg2(2)MnH2O62+
(R)eg2t2g3(3)CoNH363+
(S)t2g4eg2(4)FeCl4
  (5)CoCl4-2
 (P)(Q)(R)(S)
(1)1423
(2)1245
(3)3251
(4)3241

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a

1

b

2

c

3

d

4

answer is D.

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Detailed Solution

detailed_solution_thumbnail

(P) t2g6eg0 [Co(NH3)6]3+

(Q) t2g3eg2 [Mn(H2O)6]2+

(R) e2t23 [FeCl4]

(S) t2g4eg2 [Fe(H2O)6]2+

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