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Q.

Match the equations in List – I to solution in List – II.

         Column – I

Column – II

A)

Mn2+

P)

Flame test

B)

Pb2+

Q)

With  aq.NH3  gives white precipitate

C)

Ag+

 R)

With neutral solution of disodium hydrogen phosphate gives yellow precipitate

D)

Cu2+

 S)

Black precipitate with KCNS which slowly changes to white

 

 

 T)

Gives ppt. with dil.HCl

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a

A – PQ, B – PQT, C – RT, D – PS

b

A – PQRS, B – PRT, C – RT, D – PQS

c

A – Q, B –T, C – T, D – S 

d

A – PQ, B – PQRT, C – PRT, D - PQRS

answer is A.

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Detailed Solution

 Mn2+ gives green flashes in flame test. Also it gives white ppt. with  aq.NH3
 MnCl2+2NH4OHMn(OH)4+2NH4Cl
Pb2+ gives white precipitate with aqueous ammonia and  dil.HCl
Pb2+  shows blue colour in flame test
Pb2++2OHPb(OH2)White         Pb2++2ClPbCl2White        Ag++HPO42Ag3PO4White            Cu2++SCN2CuSCNYellow(SCN)2        2Cu(SCN)22CuSCNWhite(SCN)2

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Match the equations in List – I to solution in List – II.         Column – IColumn – IIA)Mn2+P)Flame testB)Pb2+Q)With  aq.NH3  gives white precipitateC)Ag+ R)With neutral solution of disodium hydrogen phosphate gives yellow precipitateD)Cu2+ S)Black precipitate with KCNS which slowly changes to white   T)Gives ppt. with dil. HCl