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Q.

Match the extraction processes listed in column - I with metals listed in column - II:

Column- I  Column - II
A. Self reduction P. Lead
B. Carbon reduction  Q. Silver
C. Complex formation and displacement of metalR. Copper
D. Decomposition of iodide S. Boron

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a

AR, BP, CQ, DS 

b

AR, BP, CS, DR

c

 AP, BQ, CS, DR 

d

AS, BP, CQ, DR

answer is A.

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Detailed Solution

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1. Lead is extracted from its ore by reduction with carbon and a self-reduction process.

PbO+CPb+CO 

PbS+2PbO3 Pb+SO2

2. The process of extraction of the metal silver is called as cyanide process and sodium cyanide solution is used. In this a complex formation takes place and the metal is obtained by displacement.

Ag2 S+4NaCN2NaAg(CN)2+Na2 S Zn+2NaAg(CN)2Na2Zn(CN)4+2Ag

3. Copper can be extracted in a similar process to lead.

4. As for boron, its iodide is unstable above a particular temperature. So crude metal is converted into its iodide (in a sealed container) and then the iodide is decomposed by heating to get pure metal.

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