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Q.

Match the following  

List-I

(Electronic config.)

List II

(Rules Violated)

(A) Question Image

I) Hund’s only

(B) Question Image

II) Pauli’s and Hund’s only

(C) Question Image

III) Auf-bau, Pauli’s and Hund’s

(D) Question Image

IV) Auf-bau only

V)Auf-bau and Hund’s only

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a

A-I      B-II     C-V     D-IV

b

A-II     B-I       C-IV    D-III

c

A-II     B-I       C-V     D-III

d

A-II     B-I       C-V     D-IV

answer is A.

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Detailed Solution

Aufbau’s: Lower energy orbitals must be filled first

Pauli’s: No two e- can have the same set of quantum numbers

Hund’s: Degenerate orbitals must be filled with e- with parallel spin

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