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Q.

Match the following Column-I with Column-II

                                      Column-I

Column-II

A

In a sample of H-atom for 52 transition

P

Maximum 6 spectral lines will be observed from the sample

B

In a sample of He+ion for 51 transition

Q

A photon of wavelength λ=365R can be emitted

C

In a sample of H-atom for 73 transition

R

A photon of wave number v¯=7R144 can be emitted

D

In a sample of He+-ion for 74 transition

S

When single isolated atom/ ion is considered maximum 4 spectral lines are observed for given transition

 

 

T

At least one photon is visible

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a

A-P, Q, R, T;B-S, T;C-R, S;D-P, Q, T  

b

A-P, Q, R;B-S, T;C-R, S;D-P, Q, S

c

A-P, Q, R, S;B-P, S;C-R, S;D-P, Q, S

d

A-P, Q, T;B-P, T;C-Q, R;D-P, Q, S

answer is A.

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Detailed Solution

(A) For 52  transition in H-atom sample
Max.spectral lines   =Δn(Δn+1)2=3×42=6
λ  of option corresponding to 32 transition: 1λ=R(1)2
 [122132]λ=365R
  v¯  of photon corresponding to 43  transition:  v¯=R(1)2
 [132142]v¯=7R144
For single isolated  atom, maximum spectral lines  =3(54,43,32)
(B) For  51 transition in He+  ion sample
Max.spectral lines  =n(n1)2=5×42=10
(H)32=(He+)64  (Not possible for given sample)
(H)43=(He+)86 (Not possible for given sample)
For single isolated ion, maximum spectral lines = 

=4(54,43,32,21)
(C) For 73 transition in H atom sample
Max. spectral lines= (4+1)×42=10
To emit photon of λ=365R , transition should be from  32 (Not possible)
To emit photon of  v¯=7R144  transition should be from  43 ( possible)
For single isolated atom, maximum spectral lines=  

4(76,65,54,43)
(D)  For 74  transition in He+  ion sample 
Max. Spectral lines  (3+1)×32=6
(H)32=(He+)64 (possible for given sample)
  photon of λ=365R , can be emitted
 ( Not possible for given sample)
For single isolated ion, maximum spectral lines = 3(76,65,54)
Any photo whose energy is 1.55 to 3.1 ev, will be visible

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