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Q.

Match the following columns :

 Column-I  (Molecules/species)  Column-II {Correct characteristics)
a)SO42p)All the bond lengths are equal
b)NH3q)Perfect tetrahedral shape of the molecule/ion
c)NO3r)Both σ and π bond are present
d)CHF3s)Non planar
  t)Polar

 

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a

(ap,q,t); (bp,q,r,t); (cp,r,t); (dq,r,s)

b

(aq,r,s); (br,s,t); (cq,r,t); (dr,t)

c

(ap,q,r); (bp,t); (cp,q); (dr,s)

d

(ap,q,r,s); (bp,s,t); (cp,r); (ds,t)

answer is D.

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Detailed Solution

(a) The structure of SO42,

Question Image

(P) Due to resonance (Q) Perfect tetrahedral shape (R) 4σand 2π bond are present (S) Non-planar

(b)

Question Image

(P) B.L. are same (S) Pyramidal non-planar (T) Lone pair moment and bond pair moment is not equal.

(c)

Question Image

(P) Due to resonance. (R) 3σ and 1π bond are present.

(d)

Question Image

(S) Non-planar (T) B.A. are different.

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