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Q.

Match the following columns :

column-Icolumn-II
(a) 2 lone pairs are present(p) XeF5
(b) Zero dipole moment(q) NF3
(c) Planner(r) ICl3
(d) All adjacent bond angles are equal(s) XeF4

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a

(a-p, r, s); (b-p, s); (c-p, r, s); (d-p, q, r, s)

b

(a-s, r, p); (b-p, s); (c-s, r, p); (d-r, q, p, s)

c

(a-p, r, s); (b-p, s); (c-s, r, p); (d-s, q, r, p)

d

(a-r, p, s); (b-s, p); (c-p, r, s); (d-q, p, r, s)

answer is A.

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Detailed Solution

For XeF5,

No. of electron pair =28+5+1=7

Number of bond pair =5. 

Number of lone pair =2.

Similarly in NF3ICl3, there is two lone pair present.

Due to their equal and opposite magnitudes, the dipole moments connected to the lone pairs of XeF5 and NF3 will cancel each other out.
First three are triangular with two lone pairs.
Each and every molecule has an equal number of neighboring bonds with equal angles.

 

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