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Q.

Match the following columns :

 Column-I Column-II
a)SO3p)Paramagnetic
b)SO2q)dπpπ bond
c)CO2r)Linear
d)NO2s)Planar
  t)Angular

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a

(aq,r); (bq,t); (cr,s,t); (dq,r,s,t)

b

(aq,s,t); (bp,s,t); (cq,s); (dp,r,t)

c

(aq,s); (bq,s,t); (cr,s); (dp,s,t)

d

(aq,r,s,t);(bq,r);(cr,s,t);(dp,s)

answer is C.

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Detailed Solution

Sulfur trioxide is thought of as a sulfuric acid (H2SO4) anhydride. The trigonal planar structure of SO3 has a bond angle of 120o. It displays a representation of the SO3 molecule. A triangular planar SO3 molecule with sp2 hybridization of the S atom exists in the gaseous phase.
Three sigma bonds are produced by the sp2p overlap, three bonds, one produced by the p(π)-p(π) overlap, and two by the p(π)-d(π) overlap. O-S-O bond angles measure at 120o

The bond angles for H2o, H2S, and NH3 are roughly equivalent to 109.5 degrees, whereas the bond angles for SO2 are almost 120 degrees. 

The CO2 molecule is sp-hybridized and therefore linear, while CO2- is planar and sp2-hybridized. An angular molecule called SO2 has sp2 hybridization. Tetrahedral sp3 - hybridised SO2-.
There are no lone pairs and two electron groups in carbon dioxide. Therefore, the electron-group geometry and molecular geometry of carbon dioxide are linear. The NO2 is the same.

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