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Q.

Match the following columns :

Column-IColumn-II
(a)  XeF4 (p) Central atom has sp3d2  hybridisation and +6 oxidation state
(b) XeO2 F2(q) Central atom has sp3d hybridisation and +6 oxidation state
(c)  SF6(r) Central atom has sp3d2 hybridisation and +4 oxidation state.
(d)  SOF4 (s) Bonding involves two excitation stages
 (t) Non-planar

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a

(a-r, s); (b-q, t); (c-p, s, t); (d-q, s, t)

b

(a-t, s); (b-q, t); (c-p, s, q); (d-q, r, t)

c

(a-r, t); (b-q, t); (c-p, t, s); (d-q, p, s)

d

(a-q, t); (b-q, t); (c-p, r, s); (d-q, s, t)

answer is D.

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Detailed Solution

Ground State : Covalency of Xe0
                          Covalency of S2
1st Excited State : Covalency of Xe2
                                 Covalency of S4
2nd Excited State: Covalency of Xe4
                                 Covalency of S6
3rd Excited State: Covalency of Xe6 

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Match the following columns :Column-IColumn-II(a)  XeF4 (p) Central atom has sp3d2  hybridisation and +6 oxidation state(b) XeO2 F2(q) Central atom has sp3d hybridisation and +6 oxidation state(c)  SF6(r) Central atom has sp3d2 hybridisation and +4 oxidation state.(d)  SOF4 (s) Bonding involves two excitation stages (t) Non-planar