Q.

Match the following columns :

Colwnn-1Colwnn-II
(a) NH4Cl(p) Hydrogen bond
(b) CuSO45H2O(q) Co-ordlnate bond
(c) HNC(r) Ionic bond
(d) liquid H2O2(s) Covalent bond

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a

(a-s, q, s); (b-p, s, r, s); (c-q, s); (d-p, s)

b

(a-q, r, s); (b-p, q, r, s); (c-r, q); (d-q, r)

c

(a-q, r, s); (b-s, q, r, p); (c-q, s); (d-s, p)

d

(a-q, r, s); (b-p, q, r, s); (c-q, s); (d-p, s)

answer is A.

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Detailed Solution

An ionic bond is formed between the NH4Cl ions in an NH4Cl molecule, three covalent bonds are formed between the N and three H atoms, and one coordinate bond is formed between the N and one H atom.
The solid-state structure of CuSO45H2O is depicted above. Cu2+ ions are attracted to SO 4 2 ions not only by ionic interactions (electrovalent), but also by coordinate covalent bonds.

Cu 2+ ions form coordinate covalent bonds with water and sulphate ions. Water and sulphate ions both have covalent bonds.

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