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Q.

Match the following columns :

 List-I List-II
a)CH3F<CH3Cl<CH3Brp)Dipole moment of the molecule
b)CH3F>CH3Cl>CH3Brq)Bond length (carbon halogen)
c)CH3F<CH3Cl>CH3Brr)Difference in electronegativity of C and X halogen)
d)CH3F=CH3Cl=CH3Brs)No of lone pairs

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a

pqrs
2314

b

pqrs
2134

c

pqrs
4213

d

pqrs
3142

answer is A.

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Detailed Solution

F has the highest electronegativity among the three halogens, Cl, Br, and I. As F and C are closer together in CH3F, the dipole moment decreases. CH3Cl follows CH3F, CH3Br, and CH3I. As a result, CH3Cl will possess the greatest dipole moment.

The differential in electronegativity between carbon and the halogens determines the length of the C-halogen bond in full. The bond length decreases as the difference increases.I<Br<Cl<F are the order of halogens' electronegativity. As a result, CH is the proper order in which C-halogen bond length increases.
CH3F<CH3Cl<CH3Br<CH3I.

There are no lone pairs in CH3F=CH3Cl=CH3Br.

Thus, the option A is correct.

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