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Q.

Match the following columns:

 Column-I Column-II
(a) H4P2O7(p) P0P linkage is/are present 
(b) Hypophosphoric acid(q)Acidic strength of OH group - acid present in the molecule is same 
(c) H3PO5(r) Central atom is in its highest oxidation state
(d) H4P2O5(s) All H-atoms are ionisable

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a

(a-p, s, r, q); (b-q, s); (c-r, q); (d-p, q)

b

(a-q, p, r, s); (b-r, s); (c-r, s); (d-q, p)

c

(a-p, q, r, s); (b-q, s); (c-r, s); (d-p, q)

d

(a-s, q, r, p); (b-r, s); (c-r, q); (d-p, r)

answer is C.

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Detailed Solution

H4P2O7 structure is,

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In this central atom is in its highest oxidation state and all H-atoms are ionisable.

A mineral acid having phosphorus in the +4 oxidation state is called hypophosphoric acid. Its chemical composition is H4P2O6.
The oxidation state of P is +7 in peroxophosphoric acid.

H4p2o5 structure:

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Match the following columns: Column-I Column-II(a) H4P2O7(p) P−0−P linkage is/are present (b) Hypophosphoric acid(q)Acidic strength of −OH group - acid present in the molecule is same (c) H3PO5(r) Central atom is in its highest oxidation state(d) H4P2O5(s) All H-atoms are ionisable