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Q.

Match the following columns:

Column-I(Compound/Species Column-II(HybridizationColumn-III(Bond angle 
(a) XeF5(p) sp3(w) AIl angles same and 72°
(b) SPCI3(q) sp2(x) AIl bond angles less than the bond angle in water
(c) OF2(r) sp3d3(y) Axial bond angle •177° and equatorial=  104°
(d) SF4(s) sp3d(z) One angle more than 109°28' and other angle less than 109°28'

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a

(a-r, w, x); (b-p, z); (c-p, x); (d-s, y)

b

(a-r, w, x); (b-p, y ); (c-p, z); (d-s, y)

c

(a-r, p); (b-z, p); (c-r, x); (d-w, y)

d

(a-r, p x); (b-p, z); (c-p, x); (d-p, y)

answer is A.

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Detailed Solution

Question Image

The molecule in which the aIl bond angles are smaller than those in water is called XeF5 (H2O). Have sp3d3 hybridization for molecules with a six-steric-position steric number.
sp3 hybridization with an angle more than or equal to 109°28' and an angle less than 109°28' is present in the structure of the protein SPCI3SPCI3.
Because there are two bond pairs and two lone pairs in oxygen in OF2, hybridization is sp3.
In SF4sp3d type hybridization is taking place.

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