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Q.

Match the following

 List -I (complex) List -I (electronic configuration of metal/ ion)
A[Co(NH3)6]3+It2g5eg0
B[CoF6]3IIt2g6eg0
C[Ni(CO)4]IIIt2g4eg2
D[Fe(CN)6]3IVt24e6

The correct answer is

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a

A - II, B - III, C - IV, D - I

b

A - III, B - IV, C - II, D - I

c

A - IV, B - III, C - I, D - II

d

A - II, B - I, C - IV, D - III

answer is A.

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Detailed Solution

[Co(NH3)6]3+= Co is in +3 oxidation state and NH3 is a strong ligand. Its electronic configuration is t2g6eg0

[CoF6]3= Co is in +3 oxidation state and F is a weak ligand. Its electronic configuration is t2g4eg2

[Ni(CO)4] = Nickel is in 0 oxidation state and Co is a strong ligand. Its electronic configuration is t24e6

[Fe(CN)6]3= Fe is in +3 oxidation state and CN- is a strong ligand. Its electronic configuration is t2g5eg0

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