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Q.

Match the following lists

S.No.List-IS.No.List-II
A)Grignard reagent1)H2/Pd – BaSO4
B)Clemmensen reduction2)N2H4|KOH|Glycol
C)Rosenmund reduction3)CH3MgX
D)Wolff - Kishner reduction4)Zn - Hg | conc. HCl
  5)H2 | Ni

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a

A -  3      B -  4     C -  1      D  - 2

b

A - 2       B - 1      C - 4       D  -5

c

A -   3     B -   4    C -  2      D  -1

d

A -  5      B -  3     C -  2      D  - 1

answer is B.

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Detailed Solution

The reaction of acid chlorides are converted into aldehydes by using hydrogen gas over palladium poisoned by barium sulphate is called as Rosendmund reduction.

Wolf kishner reduction is reduction of carbonyls in the presence of Hydrazine-base and ethylene glycol as solvent.

Clemensons reduction is reduction of carbonyls in the presence of  Zn-Hg/HCl.

Grignard reagent is RMgX, it involves nucleophilic addition.

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