Match the following
Column - I
Complex
Column – II
Isomerism
a) $\underset{(redform)}{{[Co {({NH}_{3})}_{5} ({NO}_{2})]}^{+ 2}}$ isomerism and $\underset{(yellow form)}{{[Co {({NH}_{3})}_{5} (ONO)]}^{+ 2}}$ i) Ionisation
b) $[Co {({NH}_{3})}_{6}] [Cr (CN)_{6}]$ and $[Cr {({NH}_{3})}_{6}] [Co (CN)_{6}]$ ii) Solvate isomerism
c) $[Co {({NH}_{3})}_{5} ({SO}_{4})] Br$ and $[Co {({NH}_{3})}_{5} Br] {SO}_{4}$ iii) Linkage isomerism
d) $[Cr {(H_{2} O)}_{6}] {Cl}_{3}$ and $[Cr {(H_{2} O)}_{5} Cl] {Cl}_{2} \cdot H_{2} O$ iv) Coordination isomerism

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a - i, b - iv, c - iii, d - ii

a - iv, b - ii, c - i, d - iii

a - ii, b - iii, c - iv, d - i

a - iii, b - iv, c - i, d - ii

answer is A.

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Detailed Solution

Column - I Complex	Column – II Isomerism
a) $\underset{(redform)}{{[Co {({NH}_{3})}_{5} ({NO}_{2})]}^{+ 2}}$ isomerism and $\underset{(yellow form)}{{[Co {({NH}_{3})}_{5} (ONO)]}^{+ 2}}$	iii) Linkage isomerism
b) $[Co {({NH}_{3})}_{6}] [Cr (CN)_{6}]$ and $[Cr {({NH}_{3})}_{6}] [Co (CN)_{6}]$	iv) Coordination isomerism
c) $[Co {({NH}_{3})}_{5} ({SO}_{4})] Br$ and $[Co {({NH}_{3})}_{5} Br] {SO}_{4}$	i) Ionisation isomerism
d) $[Cr {(H_{2} O)}_{6}] {Cl}_{3}$ and $[Cr {(H_{2} O)}_{5} Cl] {Cl}_{2} \cdot H_{2} O$	ii) Solvate isomerism