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Q.

Match the following 

 Column I Column II
A.Energy of electron in ground state of He+(i)– 6.04 eV
B.Potential energy of electron in of 1st orbit of H-atom(ii)– 27. 2 eV
C.Kinetic energy of  electron in 2nd excited state of He+(iii)8.7 x 10-18 J
D.Ionisation potential of He+(iv)– 54.4 eV
 ABCD
1.iiiiiiiv
2.iviiiiii
3.iviiiiii
4.iiiiiiiv

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a

1

b

2

c

3

d

4

answer is C.

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Detailed Solution

En=-Z2n2E1 ; -E1=-13.6 eV/atom For He+, Z=2 ; n=1....ground state,  n=3...2nd excited state, IP of He+=+13.6 Z2 eV/atom P.E = 2 T.E ....with negative sign K.E = T.E.........with positive sign

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