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Q.

Match the following

 Complex Colour
A)NiH2O4enaq2+I)Grey-green
B)Ni1H2O2en2aq2+II)Violet
C)Ni(en)3aq2+III)Blue/Purple
D)CrH2O5ClCl2H2OIV)Pale blue

The correct match is
 

 ABCD
1IVIIIIII
2IIIIIIIV
3IIVIIIII
4IIIIIVII

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a

2

b

1

c

3

d

4

answer is A.

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Detailed Solution

NiH2O4enaq2+-Pale blue

Ni1H2O2en2aq2+-Blue/Purple

Ni(en)3aq2+-Violet

CrH2O5ClCl2H2O -Grey-green

Due to d-d transition  above all compounds shows colour , for strong field ligand CFSE increases and λ value is decreases.

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