Q.

Match the following
List – I                                                List – II
A) Acetaldehyde,                           I) Enantiomers
     Vinylalcohol
B) Elipsed and                               II) Tautomers ethane
    staggered
C) (+)2-Butanol,                            III) Chain isomers
     (–) 2-Butanol
D) Methyl-n-                                  IV) Conformational
     propylamine isomers
                                                          V) Metamers

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a

   A   B   C   D
   II   IV  I   V 
 

b

   A   B   C   D
   V   I    IV    II
 

c

   A   B   C   D
   V   I    III   II 
 

d

   A   B   C   D 

   II   IV  III   V 

 

answer is B.

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Detailed Solution

  • In tautomerization, a hydrogen atom or proton may move from one atom to another. 
  • Conformational isomers are a type of stereoisomerism in which rotations are about single bonds. 
  • Chiral compounds that are superimposable mirror reflections of one another are called enantiomers.
    This type of isomerism occurs in compounds with an alkyl group surrounding a divalent element like an O or S atom or a group like -NH. Ethers and thioethers serve as examples.
    CH3NHCH2CH2CH3 and CH3CH2NHCH2CH3, are metamers.

So, option B) is correct. 

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