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Q.

Match the following:
Test/Method                       Reagent
i) Lucas Test                       a) C6H5SO2Cl/aq·KOH
ii) Dumas method             b) HNO3/AgNO3
iii) Kjeldahl's method        c) CuO/CO2
iv) Hinsberg test                d) Conc. HCl and ZnCl2
                                              e) H2SO4

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a

i – d, ii – c, iii – b, iv – e

b

i – b, ii – a, iii – c, iv – d

c

i – b, ii – d, iii – e, iv – a

d

i – d, ii – c, iii – e, iv – a

answer is D.

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Detailed Solution

A solution of anhydrous zinc chloride is used in the Lucas Test to distinguish and classify primary, secondary, and tertiary alcohols.

A chemical process called the Hinsberg test is used to differentiate between primary, secondary, and tertiary amines. The German chemist Oscar Heinrich Daniel Hinsberg initially described this reaction in 1890. The amines operate as nucleophiles and assault the electrophile in the Hinsberg Test (sulfonyl chloride).

Lucas test - Conc. HCl and ZnCl2
Dumas method - CuO/CO2
Kjeldahl's method -  H2SO4

Hinsberg Test - C6H5SO2Cl/aq·KOH

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